発表論文 (Publications)

学術論文(publications)

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2020

• Deoxyfluorination of acyl fluorides to trifluoromethyl compounds by FLUOLEAD^R/Olah’s reagent under solvent-free conditions
  Liang, Y.; Taya, A.; Zhao, Z.; Saito, N.; Shibata, N.^*
  Beilstein J. Org. Chem. 2020, 16, 3052-3058. [Abstract]
  DOI: 10.3762/bjoc.16.254
  
  
• Modular Synthesis of Medium-Sized Fluorinated and Nonfluorinated Heterocyclic Lactones by Sequential CN-Bond-Cleaving Ring Expansion under Pd Catalysis
  Uno, H.; Kawai, K.; Shiro, M.; Shibata, N.^*
  ACS Catal. 2020, 10, 14117-14126. [Abstract]
  DOI: 10.1021/acscatal.0c03927
  
  
  
  Synfact誌に紹介されました。Synfacts, 2021, 17(02), 0163, DOI: 10.1055/s-0040-1719315
  
• Synthesis of Chiral gem-Difluoromethylene Compounds by Enantioselective Ethoxycarbonyldifluoromethylation of MBH Fluorides via Silicon-Assisted C-F Bond Activation
  Sumii, Y.; Nagasaka, T.; Wang, J.; Uno, H.; Shibata, N.^*
  J. Org. Chem. 2020, 85 (23), 15699-15707. [Abstract]
  DOI: 10.1021/acs.joc.0c02201
  
  
  
  Synfact誌に紹介されました。Synfacts, 2021, 17(02), 0203, DOI: 10.1055/s-0040-1706126
  
• Design and Synthesis of a Chiral Halogen-Bond Donor with a Sp³-Hybridized Carbon-Iodine Moiety in a Chiral Fluorobissulfonyl Scaffold
  Uno, H.; Matsuzaki, K.; Shiro, M.; Shibata, N.^*
  Molecules 2020, 25(19), 4539. [Abstract]
  DOI: 10.3390/molecules25194539
  
  
• An IMiD-induced SALL4 degron system for selective degradation of target proteins
  Yamanaka, S.; Shoya, Y.; Matsuoka, S.; Nishida-Fukuda, H.; Shibata, N.; Sawasaki, T.^*
  Commun. Biol. 2020, 3, 515. [Abstract]
  DOI: 10.1038/s42003-020-01240-5
  
• Structural bases of IMiD selectivity that emerges by 5-hydroxythalidomide
  Furihata, H.; Yamanaka, S.; Honda, T.; Miyauchi, Y.; Asano, A.: Shibata, N.; Tanokura, M.^*; Sawasaki, T.^*; Miyakawa, T.^*
  Nat. Commun. 2020, 11, 4578. [Abstract]
  DOI: 10.1038/s41467-020-18488-4
  
• Aryl gem-Difluorovinyl Pinacolboronates: Synthesis and Utility for Suzuki-Miyaura Coupling Reaction
  Zhou, J.; Jiang, B.; Guo, M.: Sumii, Y.: Shibata, N.^*
  Chem. Lett. 2020, 49, 1439. [Abstract]
  DOI: 10.1246/cl.200621
  
  
• Current contributions of organofluorine compounds to the agrochemical industry
  Ogawa, Y.; Tokunaga, E.; Kobayashi, O.; Hirai, K.; Shibata, N.^*
  iScience 2020, 23, 101467. [Abstract] [Abstract(Elsevier)]
  DOI: 10.1016/j.isci.2020.101467
  
  
• Diastereoselective Synthesis of Enantioenriched Trifluoromethylated Ethylenediamines and Isoindolines Containing Two Stereogenic Carbon Centers by Nucleophilic Trifluoromethylation Using HFC-23
  Hirano, K.; Saito, T.; Fujihira, Y.; Sedgwick, D. M.; Fustero, S.; Shibata, N.^*
  J. Org. Chem. 2020, 85, 7976-7985 [Abstract]
  DOI: 10.1021/acs.joc.0c00796
  
  
• Pd-catalyzed fluoro-carbonylation of aryl, vinyl, and heteroaryl iodides using 2-(difluoromethoxy)-5-nitropyridine
  Liang, Y.; Zhao, Z; Shibata, N.^*
  Commun. Chem. 2020, 3, 59 [Abstract]
  DOI: 10.1038/s42004-020-0304-3
  
  
• Contribution of Organofluorine Compounds to Pharmaceuticals
  Inoue, M.^*; Sumii, Y.; Shibata, N.^*
  ACS Omega, 2020, 5, 10633-10640. [Abstract]
  DOI: 10.1021/acsomega.0c00830
  
  
  Front Coverに採択されました。
  
  
• Pyridine tetrafluoro-λ⁶-sulfanyl chlorides: Spontaneous addition to alkynes and alkenes in the presence or absence of photo-irradiation
  Niina, K.; Tanagawa, K.; Sumii, Y.; Saito, N.; Shibata, N.^*
  Org. Chem. Front. 2020, 7, 1276-1282. [Abstract]
  DOI: 10.1039/D0QO00339E
  
  
• Two catalytic annulation modes via Cu-allenylidenes with sulfur ylides that are dominated by the presence or absence of trifluoromethyl substituents
  Gannarapu, M. R.; Zhou, J.; Jiang, B.; Shibata, N.^*
  iScience 2020, 23, 100994 [Abstract]
  [Abstract(Elsevier)]
  DOI: 10.1016/j.isci.2020.100994
  
  
• PLZF is a new substrate of CRBN with thalidomide and 5-hydroxythalidomide
  Yamanaka, S.; Murai, H.; Saito, D.; Abe, G.; Tokunaga, E.; Iwasaki, T.; Takahashi, H.; Takeda, H.; Suzuki, T.; Shibata, N.; Tamura, K.; Sawasaki, T.^*
  bioRxiv preprint 2020, Accepted [Abstract]
  DOI: 10.1101/2020.02.28.969071
  
• Synthesis of Both Mirror Images of 9‐Membered CF₃‐Heterocycles using a Single Antipode of Chiral Ligand under Pd‐catalyzed Decarboxylative Ring‐expansion with Kinetic Resolution
  Uno, H.; Punna, N.; Tokunaga, E.; Shiro, M.; Shibata, N.^*
  Angew. Chem., Int. Ed. 2020, 59, 8187-8194. [Abstract]
  DOI: 10.1002/anie.201915021
  
  
• One-step Synthesis of 2-Hydroxy-2-(trifluoromethyl)malonates by Trifluoromethylation of 2-Oxomalonates with Ruppert-Prakash Reagent
  Hirano, K.; Yoshioka, K.; Umezu, K.; Kagawa, T.; Sumii, Y.; Shibata, N.^*
  Chem. Lett. 2020, 49, 330-333. [Abstract]
  DOI: 10.1246/cl.190942
  
  
• Synthesis of Highly Functionalized 12-Membered Trifluoromethyl Heterocycles via a Nondecarboxylative Pd-Catalyzed [6 + 6] Annulation
  Uno, H.; Imai, T.; Harada, K.; Shibata, N.^*
  ACS Catal. 2020, 10, 1454-1459. [Abstract]
  DOI: 10.1021/acscatal.9b05377