名古屋工業大学　柴田研究室

発表論文 (Publications)

学術論文(publications)

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2013

  • Regioselective 1, 4-trifluoromethylation of α, β-unsaturated ketones via a S-(trifluoromethyl) diphenylsulfonium salts/copper system
    Okusu, S.; Sugita, Y.; Tokunaga, E.; Shibata, N.
    Beilstein J. Org. Chem. 2013, 9, 2189-2193. [Abstract]
    DOI: 10.3762/bjoc.9.257
  • Stereoselective Synthesis of Vinyl Triflones and Heteroaryl Triflones through Anionic O→Cvinyl and N→Cvinyl Trifluoromethanesulfonyl Migration Reactions
    Xu, X.-H.; Taniguchi, M.; Wang, X.; Tokunaga, E.; Ozawa, T. ;Masuda, H.; Shibata, N.
    Angew. Chem. Int. Ed. 2013, 52, 12628-12631. [Abstract]
    DOI: 10.1002/anie.201307535 Cover Pictureに採択されました。
  • Enantioselective monofluoromethylation of aldehydes with 2-fluoro-1,3-benzodithiole-1,1,3,3-tetraoxide catalyzed by a bifunctional cinchona alkaloid-derived thiourea-titanium complex
    Ma, H.; Matsuzaki, K.; Yang, Y.-D.; Tokunaga, E.; Nakane, D.; Ozawa, T.; Masuda H.; Shibata, N.
    Chem. Commun. 2013, 49, 11206-11208. [Abstract]
    DOI: 10.1039/C3CC46544F
  • Enantioselective Synthesis of 5-Trifluoromethyl-2-isoxazolines and Their N-Oxides by [Hydroxy(tosyloxy)iodo]benzene-Mediated Oxidative N-O Coupling
    Kawai, H.; Okusu, S.; Tokunaga, E.; Shibata, N.
    Eur. J. Org. Chem. 2013, 29, 6506-6509. [Abstract]
    DOI: 10.1002/ejoc.201301096
  • Chiral N-Fluorodibenzenesulfonimide Analogues for Enantioselective Electrophilic Fluorination and Oxidative Fluorination
    Zhu, C.-L.; Maeno, M.; Zhang, F.-G.; Shigehiro, T.; Kagawa, T.; Kawada, K.; Shibata, N.; Ma, J.-A.; Cahard, D.
    Eur. J. Org. Chem. 2013, 29, 6501-6505. [Abstract]
    DOI: 10.1002/ejoc.201300956
  • Redox chemistry of trifluoromethyl sulfonium salts as CF3 radical sources
    Mizuta, S.; Verhoog, S.; Wang, X.; Shibata, N.; Gouverneur, V.; Medebielle M.
    J. Fluorine Chem. 2013, 155, 124-131. [Abstract]
    DOI: 10.1016/j.jfluchem.2013.07.006
  • Highly Enantioselective Monofluoromethylation of C2-Arylindoles Using FBSM under Chiral Phase-Transfer Catalysis
    Matsuzaki, K.; Furukawa, T.; Tokunaga, E.; Matsumoto, T.; Shiro, M.; Shibata, N.
    Org. Lett. 2013, 15, 3282-3285. [Abstract]
    DOI: 10.1021/ol4013102
  • Trifluoromethanesulfonyl Hypervalent Iodonium Ylide for Copper-Catalyzed Trifluoromethylthiolation of Enamines, Indoles, and β-Keto Esters
    Yang, Y.-D.; Azuma, A.; Tokunaga, E.; Yamasaki, M.; Shiro, M.; Shibata, N.
    J. Am. Chem. Soc. 2013, 135, 8782-8785. [Abstract]
    DOI: 10.1021/ja402455f
  • Phthalocyanine with Trifluoroethoxy Substituents for Organic Solar Cells
    Yamada, I.; Iida, N.; Hayashi, Y.; Soga, T.; Shibata, N.
    Jpn. J. Appl. Phys. 2013, 52, 05DA07. [Abstract]
    DOI: 10.7567/JJAP.52.05DA07
  • Transition-metal-free oxidative trifluoromethylation of unsymmetrical biaryls with trifluoromethanesulfinate
    Yang, Y.-D.; Iwamoto, K.; Tokunaga, E.; Shibata, N.
    Chem. Commun. 2013, 49, 5510-5512. [Abstract]
    DOI: 10.1039/C3CC41667D
  • Efficient Access to Trifluoromethyl Diarylpyrrolines and their N-Oxides through Enantioselective Conjugate Addition of Nitromethane to β,β-Disubstituted Enones
    Kawai, H.; Yuan, Z.; Kitayama, T.; Tokunaga, E.; Shibata, N.
    Angew. Chem. Int. Ed. 2013, 52, 5575-5579. [Abstract]
    DOI: 10.1002/anie.201301123
  • In Vivo Drug Interactions of the Teratogen Thalidomide with Midazolam: Heterotropic Cooperativity of Human Cytochrome P450 in Humanized TK-NOG Mice
    Yamazaki, H.; Suemizu, H.; Murayama, N.; Utoh, M.; Shibata, N.; Nakamura, M.;Guengerich, F. P.
    Chem. Res. Toxicol. 2013, 26, 486-489. [Abstract]
    DOI: 10.1021/tx400008g
  • Selective O-Difluoromethylation of 1,3-Diones by Bromodifluoromethylating Reagents
    Liu, G.; Wang, X.; Xu, X.-H.; Lu, X.; Tokunaga, E.; Tsuzuki, S.; Shibata, N.
    Org. Lett. 2013, 15, 1044-1047. [Abstract]
    DOI: 10.1021/ol4000313
  • Cinchona alkaloid/TMAF combination: Enantioselective trifluoromethylation of aryl aldehydes
    Kawai, H.; Mizuta, S.; Tokunaga, E.; Shibata, N.
    J. Fluorine Chem. 2013, 152, 46-50. [Abstract]
    DOI: 10.1016/j.jfluchem.2013.01.032
  • Remote Anionic Fries Rearrangement of Sulfonates: Regioselective Synthesis of Indole Triflones
    Xu, X.-H.; Taniguchi, M.; Azuma, A.; Liu, G. K.; Tokunaga, E.; Shibata, N.
    Org. Lett. 2013, 15(3), 686-689. [Abstract]
    DOI: 10.1021/ol3035559
  • Efficient direct ester condensation between equimolar amounts of carboxylic acids and alcohols catalyzed by trifluoromethanesulfonic acid (TfOH) in Solkane365mfc
    Xu, X.-H.; Azuma, A.; Taniguchi, M.; Tokunaga, E.; Shibata, N.
    RSC Adv. 2013, 3, 3848-3852. [Abstract]
    DOI: 10.1039/C3RA00132F
  • Enantioselective Synthesis of Epoxides Having a Tetrasubstituted Trifluoromethylated Carbon Center: Methylhydrazine-Induced Aerobic Epoxidation of β,β-Disubstituted Enones
    Kawai, H.; Okusu, S.; Yuan, Z.; Tokunaga, E.; Yamano, A.; Shiro, M.;Shibata, N.
    Angew. Chem. Int. Ed. 2013, 52, 2221-2225. [Abstract]
    DOI: 10.1002/anie.201209355
  • A sterically demanding organo-superbase avoids decomposition of a naked trifluoromethyl carbanion directly generated from fluoroform
    Kawai, H.; Yuan,Z.; Tokunaga, E.; Shibata, N.
    Org. Biomol. Chem. 2013, 11, 1446-1450. [Abstract]
    DOI: 10.1039/C3OB27368G
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