発表論文 (Publications)

学術論文(publications)

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2017

• Recent advancements in the synthesis of pentafluorosulfanyl (SF₅)-containing heteroaromatic compounds
  Das, P.; Tokunaga, E.; Shibata, N.^*
  Tetrahedron Lett. 2017, 58, 4803-4815. (Digest paper) [Abstract]
  DOI:10.1016/j.tetlet.2017.11.015
  
  
• Synthesis and application of trifluoroethoxy-substituted phthalocyanines and subphthalocyanines
  Mori, S.; Shibata, N.^*
  Beilstein J. Org. Chem. 2017, 13, 2273-2296. (Review) [Abstract]
  DOI: 10.3762/bjoc.13.224
  
  
• Silver-induced self-immolative Cl－F exchange fluorination of arylsulfur chlorotetrafluorides: synthesis of arylsulfur pentafluorides
  Cui, B.; Jia, S.; Tokunaga, E.; Saito, N.; Shibata, N.^*
  Chem. Commun. 2017, 53,12738-12741. [Abstract]
  DOI: 10.1039/C7CC07222H
  
  
  
  Inside Cover Pictureに採択されました。 Chem. Commun. 2017, 53,12716-12716.
  DOI: 10.1039/C7CC90464A 　　Inside Cover Picture (PDF)
  
• Synthesis of Sulfur Perfluorophenyl Compounds Using a Pentafluorobenzenesulfonyl Hypervalent Iodonium Ylide
  Wang, J.; Jia, S.; Okuyama, K.; Huang, Z.; Tokunaga, E.; Sumii, Y.; Shibata, N.^*
  J. Org. Chem. 2017, 82,11939-11945. [Abstract]
  DOI: 10.1021/acs.joc.7b01908
  
  
• Electrophilic Triflyl-arylation and Triflyl-pyridylation by Unsymmetrical Aryl/Pyridyl-λ³-iodonium Salts: Synthesis of Aryl and Pyridyl Triflones
  Das, P.; Shibata, N.^*
  J. Org. Chem. 2017, 82,11915-11924. [Abstract]
  DOI: 10.1021/acs.joc.7b01690
  
  
• Biological evaluation of both enantiomers of fluoro-thalidomide using human myeloma cell line H929 and others
  Tokunaga, E.; Akiyama, H.; Soloshonok, V. A.; Inoue, Y.; Hara, H.; Shibata, N.^*
  PLoS One 2017, 12(8): e0182152. [Abstract]
  DOI: 10.1021/acs.chemrestox.7b00127
  本論文内容のプレスリリース
  
  
• Asymmetric synthesis of α-deuterated α-amino acids
  Takeda, R.^*; Abe, H.; Shibata, N.; Moriwaki, H.^*; Izawa, K.; Soloshonok, V. A.^*
  Org. Biomol. Chem. 2017, 15, 6978-6983. [Abstract]
  DOI: 10.1039/C7OB01720K
• The Dihydroxy Metabolite of the Teratogen Thalidomide Causes Oxidative DNA Damage
  Wani, T. H.; Chakrabarty, A.; Shibata, N.; Yamazaki, H.; Guengerich, F. P.; Chowdhury, G.^*
  Chem. Res. Toxicol. 2017, 30, 1622-1628. [Abstract]
  DOI: 10.1021/acs.chemrestox.7b00127
  
• Trifluoroethoxy-Coated Phthalocyanine Catalyzes Perfluoroalkylation of Alkenes under Visible-Light Irradiation
  Matsuzaki, K.; Hiromura, T.; Amii, H.; Shibata, N.^*
  Molecules 2017, 22, 1130. [Abstract]
  DOI: 10.3390/molecules22071130
  
  
• Diastereoselective synthesis of fluoroisosteric analogues of antiparasitic pyrrolobenzoxazine alkaloids from tryptophan by successive fluorination-cyclization and a Meisenheimer-type rearrangement
  Das, B.; Tokunaga, E.; Harada, K.; Sumii, Y.; Shibata, N.^*
  Org. Chem. Front. 2017, 4, 1726-1730. [Abstract]
  DOI: 10.1039/C7QO00234C
  
  
  
  Inside Cover Pictureに採択されました Org. Chem. Front. 2017, 4, 1708-1708.
  DOI: 10.1039/C7QO90038D
  
• Induction of human cytochrome P450 3A enzymes in cultured placental cells by thalidomide and relevance to bioactivation and toxicity
  Murayama, N.: Kazuki, Y.; Satoh, D.; Arata, K.; Harada, T.; Shibata, N.; Guengerich, F. P.; Yamazaki, H.^*
  J. Toxicol. Sci. 2017, 42, 343-348. [Abstract]
  DOI: 10.2131/jts.42.343
  
• IF₅ affects the final stage of the Cl-F exchange fluorination in the synthesis of pentafluoro-λ⁶-sulfanyl-pyridines, pyrimidines and benzenes with electron-withdrawing substituents
  Cui, B.; Kosobokov, M.; Matsuzaki, K.; Tokunaga, E.; Shibata, N.^*
  Chem. Commun. 2017, 53, 5997-6000. [Abstract]
  DOI: 10.1039/C7CC02802D
  
  
• Operationally Convenient and Scalable Asymmetric synthesis of (2S)- and (2R)-α-(Methyl)cysteine Derivatives via Alkylation of Chiral Alanine Schiff Base Ni^II Complexes
  Yamamoto, J.; Kawashima, A.; Kawamura, A.; Abe, H.; Moriwaki, H.^*; Shibata, N.; Soloshonok, V. A.^*
  Eur. J. Org. Chem. 2017, 14, 1931-1939. [Abstract]
  DOI: 10.1002/ejoc.201700018
  
• SF₅-pyridylaryl-λ³-iodonium salts and their utility as electrophilic reagents to access SF₅-pyridine derivatives in the late-stage of synthesis
  Das, P.; Takada, M.; Matsuzaki, K.; Saito, N.; Shibata, N.^*
  Chem. Commun. 2017, 53, 3850-3853. [Abstract]
  DOI: 10.1039/C7CC01043E
  
  
• Trifluoroethoxy-Coated Subphthalocyanine affects Trifluoromethylation of Alkenes and Alkynes even under Low-Energy Red-Light Irradiation
  Matsuzaki, K.; Hiromura, T.; Tokunaga, E.; Shibata, N.^*
  ChemistryOpen 2017, 6, 226-230. [Abstract]
  DOI: 10.1002/open.201600172
  
  
• Construction of Fluorinated Benzoxathiin Skeleton by Successive Perfluorophenylthiolation/Cyclization of Activated α-Methylene Ketones by Perfluorophenyl Diethylaminosulfur Difluoride
  Saidalimu, I.; Suzuki, S.; Wang, J.; Tokunaga, E.; Shibata, N.^*
  Org. Lett. 2017, 19, 1012-1015. [Abstract]
  DOI: 10.1021/acs.orglett.6b03875
  
  
• Difluoromethylthiolation of Phenols and Related Compounds with a HF₂CSO₂Na/Ph₂PCl/Me₃SiCl System
  Huang, Z.; Matsubara, O.; Jia, S.; Tokunaga, E.; Shibata, N.^*
  Org. Lett. 2017, 19, 934-937. [Abstract]
  DOI: 10.1021/acs.orglett.7b00113
  
  
• Catalytic Asymmetric 1,3-Dipolar Cycloaddition of β-Fluoroalkylated α,β-Unsaturated 2-Pyridylsulfones with Nitrones for Chiral Fluoroalkylated Isoxazolidines and γ-Amino Alcohols
  Yang, X.; Cheng, F.; Kou, Y.-D.; Pang, S.; Shen, Y.-C.; Huang, Y.-Y.^*; Shibata, N.
  Angew. Chem., Int. Ed. 2017, 56, 1510-1514. [Abstract]
  DOI: 10.1002/anie.201610605
  
• New Utility of Electrophilic Trifluoromethylthiolation Reagents for the Synthesis of a Variety of Triflones
  Huang, Z.; Jia, S.; Wang, C.; Tokunaga, E.; Sumii, Y.; Shibata, N.^*
  J. Fluorine Chem. 2017, 198, 61-66. [Abstract]
  DOI: 10.1016/j.jfluchem.2016.12.012
  
  
• Synthesis of chiral (tetrazolyl)methyl-containing acrylates via silicon-induced organocatalytic kinetic resolution of Morita-Baylis-Hillman fluorides
  Nishimine, T.; Taira, H.; Mori, S.; Matsubara, O.; Tokunaga, E.; Akiyama, H.; Soloshonok, V. A.; Shibata, N.^*
  Chem. Commun. 2017, 53, 1128-1131. [Abstract]
  DOI: 10.1039/C6CC08830A
  
  
• Metabolic profiles of pomalidomide in human plasma simulated with pharmacokinetic data in control and humanized-liver mice
  Shimizu, M.; Suemizu, H.; Mitsui, M.; Shibata, N.; Guengerich, F. O.; Yamazaki, H.^*
  Xenobiotica 2017, 47, 844-848. [Abstract]