名古屋工業大学　柴田研究室

発表論文 (Publications)

学術論文(publications)

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2018

  • Understanding the Thalidomide Chirality in Biological Processes by the Self-disproportionation of Enantiomers
    Tokunaga, E.; Yamamoto, T.; Ito, E.; Shibata, N.*
    Sci. Rep. 2018, 8, 17131. [Abstract]
    DOI:10.1038/s41598-018-35457-6
    本論文内容のプレスリリース

  • Synthesis of Chiral Nonracemic α-Difluoromethylthio Compounds with Tetrasubstituted Stereogenic Centers via a Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation
    Kondo, H.; Maeno, M.; Sasaki, K.; Guo, M.; Hashimoto, M.; Shiro, M.; Shibata, N.*
    Org. Lett. 2018, 20, 7044. [Abstract]
    DOI:10.1021/acs.orglett.8b02998

  • Defluorosilylation of Fluoroarenes and Fluoroalkanes
    Cui, B.; Jia, S.; Tokunaga, E.; Shibata, N.*
    Nat. Commun. 2018, 9, 4393. [Abstract]
    DOI: 10.1038/s41467-018-06830-w

  • Super-Sensitive Protonation Behavior of Trifluoroethoxy-Substituted Phthalocyanines and Their Application to Solvent Discrimination
    Tokunaga, E.; Mori, S.; Sumii, Y.; Shibata, N.*
    ACS Omega 2018, 3, 10912-10917. [Abstract]
    DOI: 10.1021/acsomega.8b01475

  • Ortho-lithiation reaction of aryl-triflones
    Sumii, Y.; Taniguchi, M.; Xu, X.-H.; Tokunaga, E.; Shibata, N.*
    Tetrahedron 2018, 74, 5635-5641. [Abstract]
    DOI: 10.1016/j.tet.2018.07.055

  • Design and synthesis of galactose-conjugated fluorinated and non-fluorinated proline oligomers: Towards antifreeze molecules
    Sumii, Y.; Hibino, H.; Saidalimu, I.; Kawahara, H.; Shibata, N.*
    Chem. Commun. 2018, 54, 9749-9752. [Abstract]
    DOI: 10.1039/C8CC05588B

  • Direct nucleophilic trifluoromethylation of carbonyl compounds by potent greenhouse gas, fluoroform: Improving the reactivity of anionoid trifluoromethyl species in glymes
    Saito, T.†; Wang, J.†; Tokunaga, E.; Tsuzuki, S.; Shibata, N.*
    Sci. Rep. 2018, 8, 11501. [Abstract]†Equal Contribution.
    DOI: 10.1038/s41598-018-29748-1

    Scientific Reports誌の2018年度購読数上位100（67位）に選出
  • Highly C-selective difluoromethylation of β-ketoesters by using TMSCF2Br/lithium hydroxide/N,N,N-trimethylhexadecan-1-ammonium bromide
    Wang, J.; Tokunaga, E.; Shibata, N.*
    Chem. Commun. 2018, 54, 8881-8884. [Abstract]
    DOI: 10.1039/C8CC05135F

  • The CF3-DAST-induced deacylative trifluoromethylthiolation of cyclic 1,3-diketones/lactams/lactones and its extension to deacylative pentafluorophenylthiolation
    Saidalimu, I.; Yoshioka, T.; Liang, Y.; Tokunaga, E.; Shibata, N.*
    Chem. Commun. 2018, 54, 8761-8764. [Abstract]
    DOI: 10.1039/C8CC05409F

  • A small-molecule inhibitor of SOD1-Derlin-1 interaction ameliorates pathology in an ALS mouse model
    Tsuburaya, N.; Homma, K.; Higuchi, T.; Balia, A.; Yamakoshi, H.; Shibata, N.; Nakamura, S.; Nakagawa, H.; Ikeda, S.; Umezawa, N.; Kato, N.; Yokoshima, S.; Shibuya, M.; Shimonishi, M.; Kojima, H.; Okabe, T.; Nagano, T.; Naguro, I.; Imamura, K.; Inoue, H.; Fujisawa, T.; Ichijo, H.*
    Nat. Commun. 2018, 9, 2668. [Abstract]
    DOI: 10.1038/s41467-018-05127-2
  • Fluorobissulfonylmethyl Iodides: An Efficient Scaffold for Halogen Bonding Catalysts with an sp3-Hybridized Carbon-Iodine Moiety
    Matsuzaki, K.; Uno, H. Tokunaga, E.; Shibata, N.*
    ACS Catal. 2018, 8, 6601-6605. [Abstract]
    DOI: 10.1021/acscatal.8b01330

    Synfactsに紹介されました。
    Synfacts 2018, 14(10), 1095. DOI: 10.1055/s-0037-1610916 [リンク]
  • Stille cross-coupling of secondary and tertiary α-(trifluoromethyl)-benzyl chlorides with allylstannanes
    Punna, N.; Harada, K.; Shibata, N.*
    Chem. Commun. 2018, 54, 7171-7174. [Abstract]
    DOI: 10.1039/C8CC03541E

  • An eccentric rod-like linear connection of two heterocycles: Synthesis of pyridine trans-tetrafluoro-λ6-sulfanyl triazoles
    Das, P.; Niina, K.; Hiromura, T.; Tokunaga, E.; Saito, N.; Shibata, N.*
    Chem. Sci. 2018, 9, 4931-4936. [Abstract]
    DOI: 10.1039/C8SC01216D

    Front coverに採択されました。 Chem. Sci. 2018, 9, 4921-4921.
    DOI:10.1039/C8SC90115E

  • Asymmetric synthesis of α-trifluoromethoxy ketones with a tetrasubstituted α-stereogenic centre via the palladium-catalyzed decarboxylative allylic alkylation of allyl enol carbonates
    Kondo, H.; Maeno, M.; Hirano, K.; Shibata, N.*
    Chem. Commun. 2018, 54, 5522-5525. [Abstract]
    DOI: 10.1039/C8CC03131B

    Inside front coverに採択されました。 Chem. Commun. 2018, 54, 5498-5498.
    DOI:10.1039/C8CC90238K

  • Modern Approaches for Asymmetric Construction of Carbon-Fluorine Quaternary Stereogenic Centers: Synthetic Challenges and Pharmaceutical Needs
    Zhu, Y.; Han, J.*; Wang, J.; Shibata, N.*; Sodeoka, M.*; Soloshonok, V. A.*; Coelho, J. A. S.; Toste, F. D.*
    Chem. Rev. 2018, 118, 3887-3964. [Abstract]
    DOI: 10.1021/acs.chemrev.7b00778
  • Stereodivergent trifluoromethylation of N-sulfinylimines by fluoroform with either organic-superbase or organometallic-base
    Punna, N.; Saito, T.; Kosobokov, M. Tokunaga, E.; Sumii, Y.; Shibata, N.*
    Chem. Commun. 2018, 54, 4294-4297. [Abstract]
    DOI: 10.1039/C8CC01526K
  • Synthesis of Aryl Triflones through the Trifluoromethanesulfonylation of Benzynes
    Sumii, Y.; Sugita, Y.; Tokunaga, E.; Shibata, N.*
    ChemistryOpen 2018, 7, 204-211. [Abstract]
    DOI: 10.1002/open.201700204
  • Highly Diastereoselective Synthesis of Trifluoromethyl Indolines by Interceptive Benzylic Decarboxylative Cycloaddition of Nonvinyl, Trifluoromethyl Benzoxazinanones with Sulfur Ylides under Palladium Catalysis
    Punna, N.†; Das, P.†; Gouverneur, V.; Shibata, N.*
    Org. Lett. 2018, 20, 1526-1529. [Abstract]†Equal Contribution.
    DOI: 10.1021/acs.orglett.8b00237
  • Access to benzo-fused nine-membered heterocyclic alkenes with a trifluoromethyl carbinol moiety via a double decarboxylative formal ring-expansion process under palladium catalysis
    Das, P.; Gondo, S.; Punna, N.; Uno, H.; Tokunaga, E.; Shibata, N.*
    Chem. Sci. 2018, 9, 3276-3281. [Abstract]
    DOI: 10.1039/C7SC05447E

    Front Coverに採択されました。 Chem. Sci. 2018, 9, 3257-3257.
    DOI: 10.1039/C8SC90066C


    Royal Society of Chemistry (RSC) の発行する重要雑誌の中で2019年の論文引用数Top 5% (名工大HPで紹介)
  • Synthesis of 5-nitro-pyrazole triflones via [3+2] cycloaddition reaction and its application for potential insecticide
    Das, P.; Uno, H.; Tokunaga, E.; Sumii, Y.; Shibata, N.*
    Fluorine notes 2018, 116, 9-10. [Abstract]
    DOI: 10.17677/fn20714807.2018.01.05
  • Synthesis of fluoro-functionalized diaryl-λ3-iodonium salts and their cytotoxicity against human lymphoma U937 cells
    Das, P.; Tokunaga, E.; Akiyama, H.; Doi, H.; Saito, N.; Shibata, N.*
    Beilstein J. Org. Chem. 2018, 14, 364-372. [Abstract]
    DOI: 10.3762/bjoc.14.24
  • Structural basis of thalidomide enantiomer binding to cereblon
    Mori, T.; Ito, T.; Liu, S.; Ando, H.; Sakamoto, S.; Yamaguchi, Y.; Tokunaga, E.; Shibata, N.; Handa, H.*; Hakoshima, T.*
    Sci. Rep. 2018, 8, 1294. [Abstract]
    DOI: 10.1038/s41598-018-19202-7
    本論文内容のプレスリリース
  • Nucleophilic fluoroalkylation/cyclization route to fluorinated phthalides
    Inaba, M.; Sakai, Y.; Shinada, S.; Sugiishi, T.; Nishina, Y.; Shibata, N.; Amii, H.*
    Beilstein J. Org. Chem. 2018, 14, 182-186. [Abstract]
    DOI: 10.3762/bjoc.14.12
  • Anionic Triflyldiazomethane: Generation and Its Application for Synthesis of Pyrazole-3-triflones via [3+2] Cycloaddition Reaction
    Das, P.; Gondo, S.; Tokunaga, E.; Sumii, Y.; Shibata, N.*
    Org. Lett. 2018, 20, 558-561. [Abstract]
    DOI: 10.1021/acs.orglett.7b03664
  • Trifluoroethoxy-coated Subphthalocyanines Attract Small Arenes in their π-Concave Cavity
    Mori, S.; Wang, J.; Tokunaga, E.; Shiro, M.; Matsumoto, T.; Tsuzuki, S.; Shibata, N.*
    ChemPlusChem 2018, 83, 95-98. [Abstract]
    DOI: 10.1002/cplu.201700508

    Front Cover Pictureに採択されました。 ChemPlusChem 2018, 83, 92-92.
    DOI: 10.1002/cplu.201800005
    Cover Profile　 ChemPlusChem 2018, 83, 93-93. DOI: 10.1002/cplu.201800004
  • Synthesis of pyridine trans-tetrafluoro-λ6-sulfane derivatives via radical additions
    Das, P.; Takada, M.; Tokunaga, E.; Saito, N.; Shibata, N.*
    Org. Chem. Front. 2018, 5, 719-724. [Abstract]
    DOI: 10.1039/C7QO00994A

    Front Coverに採択されました。 Org. Chem. Front. 2018, 5, 709-710.
    DOI: 10.1039/C8QO90016G


  • Intramolecular Aminotrifluoromethanesulfinyloxylation of ω-Aminoalkenes by CF3SO2Na/Pd(OAc)2/PhI(OAc)2/ tBuOCl/PivOH System
    Suzuki, S.; Kamo, T.; Fukushi, K.; Tokunaga, E.; Sumii, Y.; Shibata, N.*
    Synlett 2018, 29, 425-429. [Abstract]
    DOI:10.1055/s-0036-1591720

    Cluster Cover Pageに紹介されました。
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