発表論文 (Publications)

学術論文(publications)

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2012

• C-F Bond Activation of Unactivated Aliphatic Fluorides: Synthesis of Fluoromethyl-3,5-diaryl-2-oxazolidinones by Desymmetrization of 2-Aryl-1,3-difluoropropan-2-ols
  Haufe, G.; Suzuki, S.; Yasui, H.; Terada, C.; Kitayama, T.; Shiro, M.; Shibata, N.
  Angew. Chem. Int. Ed. 2012, 52, 12275-12279. [Abstract]
  DOI: 10.1002/anie.201207304
  
  
• Efficient Difluoromethylation of sp³ Carbon Nucleophiles by Bromodifluoromethylation Reagents with Organic Bases
  Liu, G.; Wang, X.; Lu, X.; Xu, X.-H.; Tokunaga, E.; Shibata, N.
  ChemistryOpen 2012, 1, 227-231. [Abstract]
  DOI: 10.1002/open.201200033
  
  
• Cation versus Radical: Studies on the C/O Regioselectivity in Electrophilic Tri-, Di- and Monofluoromethylations of β-Ketoesters
  Yang, Y.-D.; Lu, X.; Tokunaga, E.; Tsuzuki, S.; Shibata, N.
  ChemistryOpen 2012, 1, 221-226. [Abstract]
  DOI: 10.1002/open.201200032
  
  
• Decarboxylative Allylation of Trifluoroethyl Sulfones and Approach to Difluoromethyl Compounds
  Shibata, N.; Fukushi, K.; Furukawa, T.; Suzuki, S.; Tokunaga, E.; Cahard, D.
  Org. Lett. 2012, 14, 5366-5369. [Abstract]
  DOI: 10.1021/ol302589w
  
  
• Regioselective Synthesis of Pyrazole Triflones Based on Triflyl Alkyne Cycloadditions
  Kawai, H.; Yuan, Z.; Tokunaga, E.; Shibata, N.
  Org. Lett. 2012, 14, 5330-5333. [Abstract]
  DOI: 10.1021/ol3025154
  
  
• Design and Photonic Properties of Novel Fluorinated Copolymers Bearing Phthalocyanine Side Groups
  Tillet, G.; leonardis P. D.; Alaaeddine, A.; Umeda, M.; Mori, S.; Shibata, N.; Aly, S. M.; Fortin, D.; Harvey, P. D.; Ameduri, B.
  Macromol. Chem. Phys. 2012, 213, 1559-1568. [Abstract]
  DOI: 10.1002/macp.201200076
  
• N-2-Iodobenzylcinchoninium bromide is effective for catalytic enantioselective trifluoromethylation of azomethine imines in Solkane^®365mfc
  Okusu, S.; Kawai, H.; Xu, X.-H.; Tokunaga, E.; Shibata, N.
  J. Fluorine Chem. 2012, 143, 216-219. [Abstract]
  DOI: 10.1016/j.jfluchem.2012.06.008
  
  
• 3,5-Bis(pentafluorosulfanyl)phenylboronic acid: A new organocatalyst for Conia-ene carbocyclization of 1,3-dicarbonyl compounds having terminal alkynes
  Yang, Y.-D.; Lu, X.; Tokunaga, E.; Shibata, N.
  J. Fluorine Chem. 2012, 143, 204-209. [Abstract]
  DOI: 10.1016/j.jfluchem.2012.06.007
  
  
• Regioselective Synthesis of Heteroaryl Triflones by LDA (Lithium Diisopropylamide)-Mediated Anionic Thia-Fries Rearrangement
  Xu, X.-H.; Wang, X.; Liu, G. K.; Tokunaga, E.; Shibata, N.
  Org. Lett. 2012, 14, 2544-2547. [Abstract]
  DOI: 10.1021/ol300842d
  
  
• Efficient synthesis of unsymmetrical S-(bromodifluoromethyl)diarylsulfonium salts for electrophilic bromodifluoromethylating reagents
  Liu, G.; Mori, S.; Wang, X.; Noritake, S.; Tokunaga, E.; Shibata, N.
  New J. Chem. 2012, 36, 1769-1773. [Abstract]
  DOI: 10.1039/C2NJ40255F
  
  
• Fundamental Study on Organic Solar Cells Based on Soluble Zinc Phthalocyanine
  Yamada, I.; Umeda, M.; Hayashi, Y.; Soga, T.; Shibata, N.
  Jpn. J. Appl. Phys. 2012, 51, 04DK09. [Abstract]
  DOI: 10.1143/JJAP.51.04DK09
  
• In Vivo Formation of Dihydroxylated and Glutathione Conjugate Metabolites Derived from Thalidomide and 5-Hydroxythalidomide in Humanized TK-NOG Mice
  Yamazaki, H.; Suemizu, H.; Shimizu, M.; Igaya, S.; Shibata, N.; Nakamura, M.; Chowdhury, G.; Guengerich F. P.
  Chem. Res. Toxicol. 2012, 25, 274-276. [Abstract]
  DOI: 10.1021/tx300009j
  
• Organocatalytic Asymmetric Synthesis of Trifluoromethyl-substituted Diarylpyrrolines via Enantioselective Conjugated Cyanation to β-Aryl-β-trifluoromethyl-disubstituted Enones
  Kawai, H.; Okusu, S.; Tokunaga, E.; Sato, H.; Shiro, M.; Shibata, N.
  Angew. Chem. Int. Ed. 2012, 51, 4959-4962. [Abstract]
  DOI: 10.1002/anie.201201278
  
  
• Enantioselective 5-endo-dig Carbocyclization of β-Ketoesters with Internal Alkynes Employing a Four-Component Catalyst System
  Suzuki, S.; Tokunaga, E.; Reddy, D. S.; Matsumoto, T.; Shiro, M.; Shibata, N.
  Angew. Chem. Int. Ed. 2012, 51, 4131-4135. [Abstract]
  DOI: 10.1002/anie.201201060
  
  
• Organic Base-catalyzed Stereodivergent Synthesis of (R)- and (S)-3-Amino-4,4,4-trifluorobutanoic Acids
  Shibata, N.; Nishimine, T.; Shibata, N.; Tokunaga, E.; Kawada, K.; Kagawa, T.; Sorochinsky, A. E.; Soloshonok, V. A.
  Chem. Commun. 2012, 48, 4124-4126. [Abstract]
  DOI: 10.1039/C2CC30627A
  
  
• Catalytic Enantioselective Synthesis of β-Trifluoromethyl pyrrolines
  Kawai, H.; Kitayama, T.; Tokunaga, E.; Matsumoto, T.; Sato, H.; Shiro, M.; Shibata, N.
  Chem. Commun. 2012, 48, 4067-4069. [Abstract]
  DOI: 10.1039/C2CC18049A
  
  
• Partially Saturated Fluorinated Heterocycles: Diastereo- and Enantioselective Synthesis of β-Trifluoromethyl-pyrroline Carboxylates
  Kawai, H.; Sugita, Y.; Tokunaga, E.; Sato, H.; Shiro, M.; Shibata, N.
  Chem. Commun. 2012, 48, 3632-3634. [Abstract]
  DOI: 10.1039/C2CC18052A
  
  
• Suzuki-Miyaura Cross-Coupling Reactions in a Solkane365/227/Ethanol Blend at Ambient Temperature
  Xu, X.-H.; Azuma, A.; Kusuda, A.; Tokunaga, E.; Shibata, N.
  Eur. J. Org. Chem. 2012, 1504-1508. [Abstract]
  DOI: 10.1002/ejoc.201101783
  
  
• Synthesis of Isoxazole Triflones
  Kawai, H.; Sugita, Y.; Tokunaga, E.; Shibata, N.
  Eur. J. Org. Chem. 2012, 1295-1298. [Abstract]
  DOI: 10.1002/ejoc.201101814